Recherche

Research fields

Thème 1 : Modulations texturale et chimique de la charpente de matériaux poreux synthétisés par voie sol-gel

​​- Silices mésoporeuses de diamètres de pores modulable de 2 nm à 40 nm

- Autres oxydes mésoporeux (TiO2, ZrO2) et carbones poreux


Thème 2 : Modulation chimique de la surface interne de matériaux poreux

​​- Greffage post-synthétique de fonctions organiques 

- Fonctionnalisation "one-pot" de fonctions organiques ou biologiques 

​Principaux domaines d'applications : santé et environnement


• Thème 3 : Utilisation des pores comme nanoréacteurs chimiques et comme réservoirs

​​- Synthèse in-situ de nanoparticules d'Ag et Au dans des silices mésoporeuses : 

   détection de molécules et biomolécules à de faibles concentrations par spectroscopie Raman

- Synthèse in-situ de nanoparticules de Ni dans des carbones poreux : 

Adsorption de H2 / Stockage d'hydrogène

Principaux domaines d'applications : santé et énergie

 

Research responsibilities

• Porteuse du projet  A*MIDEX PR2I DIAMOND (2014-2016)                                DesIgn of Advanced functional Materials : towards applicatiONs for the Detection of low concentrated biomarkers  (2014-2016)

Laboratoires ou structures impliqués : MADIREL (Responsable V. Hornebecq) / ICR (Responsable T. Phan) / IMBE (Responsable D. Bergé-Lefranc)/ AP-HM (Responsable R. Guieu) 
Porteuse du projet CARNOT STAR DEMON (2014)                                      DEtection de bioMOlécules par des Nanocomposites poreux : effet SERS et étude thermodynamique                  Personnes impliquées : ICR ( T. Phan) / IMBE (D. Bergé-Lefranc) / PIIM (C. Pardanaud) / IM2NP (A. Merlen)

 

Referee in the following scientific journals

Microporous and Mesoporous Materials, Langmuir, Chemistry of Materials , Journal of Physical Chemistry, Journal of Hazardous Materials, Industrial & Engineering Chemistry Research, Applied Surface Science

PhD advisor

- Eva BENOVA (Popjakova) (09/2015-09/2019): Doctorat en co-tutelle avec Pr. V. ZELENAK, Université P. J. SAFARIK, Kosice, Slovaquie.

Sujet : DESIGN OF NANOPOROUS ADVANCED MATERIALS FOR CONTROLLED DRUG RELEASE 

 

- Déborah FERNAND (10/2011-12/2014)

Sujet : Porous Nanocomposites Based of Metal Nanoparticles: from Synthesis towards Applications in the Field of Adsorption 

 

- Emily BLOCH (10/2006-11/2009)

Sujet : Elaboration contrôlée de nouveaux matériaux mésoporeux pour l’adsorption de CO en présence de CO2

 

- Christina Knoefel (10/2005-01/2009)

Sujet : Synthesis, characterisation and evaluation of porous materials for the adsorption of carbon dioxide 

 

Scientific impact

Publications (2010-2016)

Detection of Rhodamine 6G at low concentrations using Raman Spectroscopy: A comparison between Ag and Au-based nanoporous substrates

D. Fernand, D. Berge-Lefranc, C. Pardanaud, T. N. Phan, A. Merlen, V. Hornebecq

European Physical Journal-Special Topics 224 (9), 2001-2010 (2015).

 

Self-assembled liquid crystalline nanoparticles as an ophthalmic drug delivery system. Part II: Optimization of formulation variables using experimental design

D. Achouri, M. Sergent, A. Tonetto, P. Piccerelle, V. Andrieu, V. Hornebecq

Drug Development and Industrial Pharmacy 41 (3), 493-501 (2015).

 

Self-assembled liquid crystalline nanoparticles as an ophthalmic drug delivery system. Part I: influence of process parameters on their preparation studied by experimental design

D. Achouri, V. Hornebecq, P. Piccerelle, V. Andrieu, M. Sergent

Drug Development and Industrial Pharmacy 41 (1), 109-115 (2015).

 

Adsorption of Rhodamine 6G on SiO2 and Ag@SiO2 Porous Solids: Coupling Thermodynamics and Raman Spectroscopy

D. Fernand, C. Pardanaud, D. Berge-Lefranc, P. Gallice, V. Hornebecq

Journal of Physical Chemistry C, 118, 28, 15308 (2014).

 

Hosting Various Guests Including Fullerenes and Free Radicals in Versatile Organic Paramagnetic bTbk Open Frameworks

D. Bardelang, M. Giorgi, V. Hornebecq, A. Stepanov, M. Hardy, E. Rizzato, V. Monnier, M. B.  Zaman, G. Chan, K. Udachin, G.  Enright, P. Tordo, O. Ouari

Crystal Growth & Design, 14, 2, 467 (2014).

 

Organic multishell isostructural host-guest crystals: fullerenes C-60 inside a nitroxide open framework

D. Bardelang, M. Giorgi, C. Pardanaud, V. Hornebecq, E. Rizzato, P. Tordo, O. Ouari

Chemical Communications, 49, 34, 3519 (2013).

 

Bottom-up solution chemistry approaches for nanostructured thermoelectric materials

R. Benoit, V. Hornebecq, F. Weill, L. Lecren, X. Bourrat, M. Treguer-Delapierre

Journal of Materials Chemistry A, 1, 45, 14221 (2013).

 

Synthesis and structural characterization of new ruthenium(II) complexes and investigation of their antiproliferative and metastatic effect against human lung cancer (A549) cells

P. Kalaivani, R. Prabhakaran, P. Poornima, R. Huang, V. Hornebecq, F. Dallemer, V. V. Padma, K. Natarajan

RSC ADVANCES, 2, 43, 20363 (2013).

 

In-situ study of electrochromic properties of self-assembled TiO2

I. Hanzu, V. Hornebecq, T. Djénizian, P. Knauth

Comptes rendus de Chimie, 16, 1, 96 (2013).

 

Electrochemical fabrication and properties of highly ordered Fe-doped TiO2 nanotubes

N. A. Kyeremateng, V. Hornebecq, H. Martinez, P. Knauth and T. Djénizian,

A European Journal of Chemical Physics and Physical Chemistry, 13, 16, 3707 (2012).

 

Computanional investigation of the adsorption of carbon dioxide onto zirconium oxide clusters

P. Boulet, C. Knöfeln B. Kuchta, V. Hornebecq and P. L. Llewellyn

Journal of Molecular Modeling, 18, 11, 4819 (2012).

 

The rigid biradical bTbk self-assembles in crystalline open frameworks and can host guests as divers as free radical TEMPO and fullerences C60 and C70

D. Bardelang, M. Giorgi, V. Hornebecq, A. Stepanov, E. Rizzato, Md. B. Zaman, G. Chan, K. Udachin, G. Enright, O. Ouari and P. Tordo,

RSC Advances, 2, 13, 5605 (2012).

 

Properties of Sn-doped TiO2 nanotubes fabricated by anodization of co-sputerred Ti-Sn thin films

N. A. Kyeremateng, V. Hornebecq, P. Knauth, T. Djénizian

Electrochimica Acta, 62, 192-198 (2012).

 

Adsorption of Carbon Dioxide on Mesoporous Zirconia: Microcalorimetric Measurements, Adsorption Isotherm Modeling and Density Functional Theory Calculations

V. Hornebecq, C. Knoefel, P. Boulet, B. Kuchta and P. L. Llewellyn

Journal of Physical Chemistry C, 115, 10097-10103 (2011).

 

Adsorption of CO and CO2 in large pore sized Ag@SiO2 nanocomposite

E. Bloch, P. L. Llewellyn, F. Chaspoul, D. Vincent and V. Hornebecq,

Journal of Physical Chemistry C, 114, 22652-22658 (2010).

 

The extraction of creatinine from physiological medium by a microporous solid and its quantification by diffuse reflectance UV spectroscopy

D. Bergé-Lefranc, O. Schaf, R. Denoyel, J.-L. Bergé-Lefranc, R. Guieu, P. Brunet and V. Hornebecq,

Microporous and Mesoporous Materials, 129, 144-148 (2010).

 

Green solvent extraction of a triblock copolymer from mesoporous silica : application to adsorption of carbon dioxide under static and dynamic conditions

C. Knofel, M. Lutecki, C. Martin, M. Mertens, V. Hornebecq and P. Llewellyn,

Microporous and Mesoporous Materials, 128, 26-33 (2010).

 

 

 

 

 


 

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