Energy and Adsorption of Powders and Porous Solids (EnAp)
Group leader: Sandrine Bourrelly |
Our group focuses on the fundamental understanding of adsorption on nanostructured and/or nanoporous materials, principally in view of applications in gas storage and gas separation. This work includes several aspects ranging from materials synthesis, their characterization via thermal methods and gas adsorption, to more complex thermodynamic and structural studies of the adsorbed phase using both experimental and computer simulation methods. Adsorption is a universal phenomenon that can be found in a wide range of domains in science and technology where nanostructured and nanoporous solids play a central role in adsorption based processes (gas storage, separation, ...). It is essential to be able to both characterize the materials involved and understand the adsorption phenomena in play. The “Energy and Adsorption” (EnAP) group works to fill gaps in our understanding in these two areas with a focus on societal relevant applications in order to strengthen the link between blue sky research and product development. From a fundamental standpoint, our knowledge base consists of a three pronged approach :
Our unique experimental approaches are the main reason for our attractiveness, which, coupled with our knowledge base has allowed us to develop a number of strategic collaborations both nationally and internationally. These collaborations have been successful in terms of project funding and valorization (high level publications, invited talks, …). Note that several of these projects (see below) have been coordinated by the group. The research topics that we have focused on in the last few years have essentially replied to Horizon 2020 targets of ‘climate change’ and ‘energy’. |
Experimental Expertise |
We are able to follow gas adsorption under a wide variety of conditions :
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Permanent Staff |
The group currently comprises of 7 permanent staff. Over our last assessment period an average of 22 articles were published per year with an average impact factor of >4. Most of our work is carried out in the framework of national or international programs of which several are coordinated by us.
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Currently hosted non-permanent staff |
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Previous collaborators |
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National and International projects |
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Local and Regional Projects |
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Recent Publication Highlights |
- Adsorption Contraction Mechanics: Understanding Breathing Energetics in Isoreticular Metal-Organic Frameworks, S. Krause, J.D. Evans, V. Bon, I. Senkovska, S. Ehrling, U. Stoeck, P. Yot, P. Iacomi, P. Llewellyn, G. Maurin, F.-X. Coudert, S. Kaskel, J. Phys. Chem. C, 2018, 122(33), 19171-19179 (DOI. 10.1021/acs.jpcc.8b04549)
- A promising metal-organic framework (MOF), MIL-96(Al) for CO2 separation under humid conditions, V. Benoit, N. Chanut, R. S. Pillai, M. Benzaqui, I. Beurroies, S. Devautour-Vinot, C. Serre, N. Steunou, G. Maurin, P. L. Llewellyn, J. Mater. Chem. A, 2018, 6, 2081-2090 (DOI. 10.1039/c7ta09696h)
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Revisiting the Aluminum Trimesate-based MOF (MIL-96): from Structure Determination to the Processing of Mixed Matrix Membranes for CO2 Capture, M. Benzaqui, R.S. Pillai, A. Sabetghadam, V. Benoit, P. Normand, J. Marrot, N. Menguy, D. Montero, W. Shepard, A. Tissot, C. Martineau-Corcos, C. Sicard, M. Mihaylov, F. Carn, I. Beurroeis, P.L. Llewellyn, G. De Weireld, K. Hadjiivanov, J.Gascon, F. Kapteijn, G. Maurin, N. Steunou, C. Serre, Chem. Mater., 2017, 29 (24), 10326–10338 (DOI. 10.1021/acs.chemmater.7b03203)
Adsorption induced structural phase transformation in nanopores, B. Kuchta, E. Dundar, F. Firmalik, P. L. Llewellyn & L. Firlej, Angewandte Chemie Int. Ed., 2017, 56(51), 16243–16246 (DOI. 10.1002/ange.201708993)
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Investigating Unusual Organic Functional Groups to Engineer the Surface Chemistry of Mesoporous Silica to Tune CO2–Surface Interactions, E. Bloch, E. Besson, S. Queyroy, R. Llewellyn, S. Gastaldi, P.L. Llewellyn, ACS Appl. Mater. Interfaces, 2017, 9(16), 14490–14496 (DOI. 10.1021/acsami.7b0090)
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Silica materials with wall-embedded nitroxides provide efficient polarization matrices for dynamic nuclear polarization NMR, E. Besson, F. Ziarelli, E. Bloch, G. Gerbaud, S. Queyroy, S. Viel, S. Gastaldi, Chem. Commun., 2016, 52, 5531-5533 (DOI : 10.1039/C6CC01809B) [web]
- Mechanical energy storage performances of an Aluminum Fumarate Metal–Organic Framework, P. G. Yot, L. Vanduyfhuys, E. Alvarez, J. Rodriguez, J.-P. Itié, P. Fabry, N. Guillou, T. Devic, I. Beurroies, P. L. Llewellyn, V. Van Speybroeck, C. Serre, G. Maurin, Chemical Science, 2016, 7, 446-450 (DOI: 10.1039/C5SC02794B) [web]
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Methane storage in flexible metal-organic frameworks with intrinsic thermal management, J. A. Mason, J. Oktawiec, M. K. Taylor, M. R. Hudson, J. Rodriguez, J. E. Bachman, M. Gonzalez, A. Guagliardi, C. M. Brown, P. L. Llewellyn, N. Masciocchi, J. R. Long, Nature, 2015, 527, 357–361.
(DOI : 10.1038/nature15732) [web] -
Oxidation Mechanism of Aluminum Nanopowders, M.-V. Coulet, B. Rufino, P.-H. Esposito, T. Neisius, O. Isnard, R. Denoyel, J. Phys. Chem. C, 2015, 119(44), 25063-25070. (DOI: 10.1021/acs.jpcc.5b07321) [web]
- The direct heat measurement of mechanical energy storage metal-organic frameworks., Rodriguez, J., Beurroies, I., Loiseau, T., Denoyel, R., Llewellyn P.L., Angewandte Chemie Int. Ed., 2015, 54(15), 4626-30 (10.1002/anie.201411202) [web]